Abstract Agile Supply Chain Dynamic Alliance based on the formation and rapid disintegration of the reconstruction and adjustment. Integrity of the agile supply chain can improve the coordination mechanism between enterprises and the supply-demand relationship, provide direct market information and extensive sales channels and improve overall efficiency of enterprises. Agile Supply Chain Dynamic synergy is an important factor restricting its development, the paper based Web services on the basis of a framework for dynamic collaboration, and used the system to design knowledge service platform in order to better use of knowledge of agile supply chain to win advantage for enterprises.